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Armour Etch Glass Etching Cream
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Glass EtchantStructure such as solid, liquid, aerosol etc.
Form: creamDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 2024176-180 Fifth Avenue
Hawthorne NJ 07506
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)Barium sulfate 007727-43-7 0-6 No Sulfuric acid 007664-93-9 0-9 Yes Ammonium hydrogen difluoride 001341-49-7 21-27 No Sodium bifluoride 001333-83-1 7.0-12.0 No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID headings to sort values.
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Barium sulfate 007727-43-7 231-784-4 0-6 -------- ------- ---- No Sulfuric acid 007664-93-9 231-639-5 0-9 H314 ------- No Ammonium hydrogen difluoride 001341-49-7 215-676-4 21-27 H301, H314 P260, P280, P301+P330+P331, P303+P361+P353, P305+P351+P338, P309+P311 No Sodium bifluoride 001333-83-1 215-608-3 7.0-12.0 H301, H314 ------- No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Material Safety Data Sheet(MSDS) Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product.
MSDS DATE :January 01, 2009 Date when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
MSDS Verified :November 09, 2009 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING3 0 1 -
Acute health effects
From MSDS:
Health Hazard Data
EFFECTS OF OVEREXPOSURE
Routes of Entry: Skin, eyes, respiratory system.
Eye Contact: May cause severe irritation with possible corneal burns.
Skin Contact: Causes severe burns and fluoride-like burns which may not be immediately evident. Skin contact may cause hypocalcemia by skin absorption. The fluoride components of this product can penetrate the skin and destroy the deep tissue layers, including bone tissue. This damage to the body's tissues may continue for days, as the fluoride ion reacts with the calcium in the skin and bone. Severe skin-contact exposures (especially when the skin contamination exceeds 160 Sq. Cm.) can cause hypocalcemia, a life-threatening lowering of serum calcium in the body.
Inhalation: May cause irritation to the respiratory tract and lung damage if exposure is excessive. Inhalation may lead to hypercalcemia, due to absorption of the fluoride components. There are several reports of death due to acute hypersensitivity reaction and acute inflammation of the bronchi and peripheral airways after accidental inhalation of barium sulfate.
Ingestion: Can cause very serious damage to the mouth, esophagus, stomach, and other tissues with which contact is made. Reported symptoms of ingestion of fluoride salts, such as in this product include salivation, nausea. Repeated small doses may produce no other symptoms, but polyuria and polydipsia have also been reported. Large doses lead promptly to burning or crampy abdominal pain, intense vomiting and diarrhea, often with hematemesis and melena, dehydration and thirst, muscle weakness, tremors, and rarely transient epileptiform convulsions, preceded or followed by progressive central nervous depression (lethargy, coma and respiratory arrest, even in the absence of circulatory failure), shock characterized by pallor, weak and thready pulse (sometimes irregular), shallow unlabored respiration, weak heart sounds, wet cold skin, cyanosis, anuria, dilated pupils, followed almost invariably by death in 2 to 4 hours. Even in the absence of shock, arrhythmias may occur, especially multiple episodes of ventricular fibrillation leading eventually to cardiac arrest. If the victim survives a few hours, paralysis of the muscles of deglutition, carpopedal spasm, and painful spasms of the extremities, occasionally localized or generalized urticaria. The above signs and symptoms are related to a variety of metabolic disorders that may occur in acute fluoride poisoning, including hypocalcemia, hypomagnesaemia, metabolic and/or respiratory acidosis and sometimes hyperkalemia. Ingestion may be fatal.
Medical conditions generally aggravated by exposure: May aggravate existing medical conditions such as allergies, dermatitis, asthma, bronchitis or any other respiratory ailment. -
Chronic health effects
From MSDS:
Chronic, low-level inhalation exposure may cause bronchitis, dental erosion and perforation of the nasal septum. Chronic, low level inhalation may also cause baritosis, which is benign form of pneumoconiosis, due to the Barium Sulfate component.
Exposure to Fluorides over years may produce mottling of tooth enamel, embrittlement and decalcification of bones and increased calcification of ligaments and vertebrae resulting in spinal stiffness (fluorosis). Repeated exposure may cause dental erosion, jaw necrosis, nasal ulceration, asthma, bronchitis and other respiratory ailments. -
Carcinogenicity
No information provided -
Handling information
All employees who handle this material should be trained to handle it safely. Avoid breathing mists or sprays generated by this product. Use in a well-ventilated location. Open containers slowly on a stable surface. Containers of this product must be properly labeled. Empty containers may contain residual product; therefore, empty containers should be handled with care. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. DO NOT STORE IN GLASS CONTAINERS. Store away from incompatible materials. Material should be stored in secondary containers or in a diked area, as appropriate. Keep container tightly closed when not in use. Storage areas should be made of fire and corrosion resistant materials. If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage to ensure containers are properly labeled and not damaged.
WORK PRACTICES AND HYGIENE PRACTICES:
Avoid all contact with this material. All employees who handle this material should be trained to handle it safely. Avoid breathing mists or sprays generated by this material. Wash thoroughly after handling this material. All personal protective equipment, tools, etc. should be neutralized thoroughly with sodium carbonate or dilute ammonia after each use. Check gloves DAILY for pinhole leaks. Discard defective gloves. Never touch outer surfaces of gloves after use. Wash contaminated clothing before reuse. Destroy contaminated shoes. Do not eat or drink while handling this material. All work practices should minimize the release of this material. Eyewash stations and safety showers should be in areas of use of this material. Calcium gluconate gel should be readily accessible in areas where potential exposure to this product exists. -
Disposal information
Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures. -
First Aid
INHALATION: If inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek immediate medical attention,
SKIN CONTACT: If the product contaminates the skin, immediately begin decontamination with running water. Minimum flushing is for 15 minutes. Do not interrupt flushing. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Do not reuse clothing or shoes until cleaned. Do not apply oils or ointments unless ordered to by a physician. Victim must seek immediate medical attention.
EYE CONTACT: If product enters the eyes, open victims eyes while under gently running water. Use sufficient force to open eyelids. Have victim ***roll*** eyes. Minimal flushing is for 15 minutes. Do not interrupt flushing. Seek immediate medical attention.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Rinse mouth with water immediately. Victim should drink large quantities of water. If milk is available, victim should drink it after drinking water. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow.
NOTE: In the event the symptoms of fluoride poisoning develop, refer to ***Recommendations to Physicians*** below.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. All personnel providing treatment must be gloved. If symptoms of fluoride poisoning develop, treatment recommendations for contamination are as follows:
SKIN CONTACT: After 15 minute water flush (if flush has not yet been done), apply calcium gluconate gel (2.16.33percent concentration) until pain has subsided, but not longer than 30 minutes. If pain lasts longer than 15 minutes, proceed with calcium gluconate injections.
EYE CONTACT: After 15 minutes water flush (if flush has not been done), flush eyes with 1 percent calcium gluconate gel in normal, sterile saline.
INHALATION: Provide 100 percent oxygen, followed by inhalation of a mist containing 2 percent calcium gluconate in saline solution. Watch for pulmonary edema.
INGESTION: Gastric lavage with lime water or milk.
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